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双语推荐:烷氧基

3-烷氧基-2-羟基丙基氟化铵的热失重行为进行研究。采用两种不同的动力学方程,即Coats—Redfen法、Mad.husudhanan—Krishnan-Ninan(MKN)法,算出3-烷氧基-2-羟基丙基氟化铵热分解反应的反应级数n、活化能E、频率因子A等动力学参数。结果表明:3-烷氧基-2-羟基丙基氟化铵热分解是一个阶段完成,反应为一级反应,表观活化能大小与烷氧基碳链长度有关,难易程度与烷氧基的碳链长度有关;其热分解表观活化能随烷氧基碳链数增加起初基本不变,当碳链数达到16时略有降低。其原因为烷氧基碳链较小时,烃基供电子能力起主要作用;当碳链数达到16时。烃基空间位阻逐渐起主要作用。
Thermo gravimetric behavior of 3-alkoxy-2-hydroxypropyl ammonium fluoride was studied using two different kinetic equations,i.e. Coats-Redfen law,Madhusudhanan-Krishnan-Ninan(MKN). Dynamic parameters of reaction order n,activation energy E,frequency factors A for 3-alkoxy-2-hydroxypropyl ammonium fluoride thermal decomposition reaction were calculated. The results show that 3-alkoxy-2-hydroxypropyl ammonium fluoride thermal decomposition is completed in a stage,and the reaction is a first order reaction,the size of the apparent activation energy is related to alkoxy carbon chain length,the difficulty degree of thermal decomposition of 3-alkoxy-2-dihydroxypropyl ammonium fluoride is related to the length of the carbon chain of alkoxy. The apparent activation energy of thermal decomposition is basically unchanged at first with the increase of the number of alkoxy carbon chain,and slightly lowers when the number of carbon chain reaches 16. The reason for the smaller alkoxy chain is that e

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1-基-1-烷氧基-1-硫基甲类化合物是缩醛化合物的一个烷氧基被一个硫基取代的产物,可以看作是缩醛与硫醇的取代产物,这类化合物由于其结构和性能的特殊性,在有机合成和香料工业中有着广泛的应用前景.本文就1-基-1-烷氧基-1-硫基甲类化合物的合成作一综述.
l-alkyl-1-alkoxyl-1-alkylthiomethane is a compound which a alkoxyl of acetal has been substituted by a alkylthio radical, and was also looked as the substitution of acetal and thiol. There is wildly application in organic synthesis and perfume industry since their special structure and function. This paper made a summary of synthesis of 1-alkyl-1-alkoxyl-1-alkylthiomethane.

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以八甲基环四硅氧(D4)、苯基三(二甲基硅氧基)硅(PTDMS,俗称三氢封头剂)或四(二甲基硅氧基)硅(TDMS,俗称四氢封头剂)为原料,通过开环聚合法合成了三端氢基聚硅氧(PDMS-H3)和四端氢基聚硅氧(PDMS-H4);再将其与甲基丙烯酸叔丁酯(t-BMA)在氯铂酸-四氢呋喃(THF)溶液催化下通过硅氢加成反应得到三端酯基聚硅氧(PDMS-t-BMA3)和四端酯基聚硅氧(PDMS-t-BMA4);最后在浓硫酸催化下水解制得三端羧基聚硅氧(PDMS-COOH3)和四端羧基聚硅氧(PDMS-COOH4)。采用FT-IR、1H NMR和GPC对各阶段产物的结构和摩尔质量及其分布进行表征。结果表明,通过开环聚合、硅氢加成、酸性水解三步反应能够获得结构清晰、摩尔质量可控的多臂端羧基聚硅氧,且叔丁酯基聚硅氧酸性水解反应效率高,后处理简单,对硅氧主链的影响较小。
With octamethylcyclotetrasiloxane (D4 ),tris (dimethylsiloxy) phenylsilane (PTDMS ) or tetrakis (dimethylsiloxy)-silane (TDMS )as raw materials,hydrogen terminated polydimethylsilox-anes (PDMS-Hx,x=3,4)were synthesized via ring-opening polymerization.Then tert-butyl methacry-late (t-BMA)was grafted to PDMS-Hx via hydrosilylation to prepare ester terminated polydimethylsilox-anes (PDMS-t-BMAx,x=3,4)with H2PtCl6 as catalyst,and the multi-branched carboxyl terminated polydimethylsiloxanes (PDMS-COOHx,x=3,4)were prepared by subsequent hydrolysis reaction under acid.The structures and molecular weights of the products were characterized by FT-IR,1 H NMR and GPC.Results show that multi-branched carboxyl terminated polydimethylsiloxanes with certain structures and molecular weights can be synthesized under control via a three-step procedure:ring-opening polymeri-zation,hydrosilylation reaction and acid hydrolysis reaction.The acid hydrolysis of polydimethylsiloxanes with a tertiary-butyl este

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以端羟基聚二甲基硅氧(107硅橡胶)为基胶、甲基三甲氧基和乙烯基三甲氧基为交联剂、纳米碳酸钙和气相法白炭黑为补强填料、硅偶联剂为增粘剂,有机钛为催化剂,制得单组分脱醇型室温硫化(RTV-1)硅橡胶。研究了基胶黏度,填料、交联剂、增粘剂的种类和用量对脱醇型RTV-1硅橡胶性能的影响。较佳配方为:100份黏度50 000 mm2/s的107硅橡胶、5份甲基三甲氧基与乙烯基三甲氧基按质量比7∶3复配的交联剂、0.4~0.6份自制氨基硅偶联剂。按此配方制得的RTV-1硅橡胶的性能较好。
Dealcoholized one component room temperature vulcanizing ( RTV-1 ) silicone rubber was pre-pared by α,ω-silanol terminated polydimethylsiloxane (107 silicone rubber) as the basic gel, methyltrime-thoxysilane and vinyltrimethoxysilane as the cross linker , and the nano-CaCO3 and fumed silica as fillers , si-lane coupling agent as the tackifier , organic titanium as the catalyst .The effects of the viscosity of 107 silicone rubber and the content of the fillers , crosslinker and coupling on the properties of RTV-1 silicone rubber were studied .The preferred RTV-1 silicone rubber formulation was that with 100 parts 107 rubber of 50 000 mPa· s viscosity , 5 parts of cross linker of methyltrimethoxysilane/vinyltrimethoxysilane ( mass ratio 7∶3 ) , 1 part of silane coupling agent with amino .The prepared RTV-1 silicone rubber had good performance .
以3-(2,3-环氧丙氧)丙基三甲氧基(KH-560)为单体,在异丙醇为溶剂、四甲基氢氧化铵(TMAH)为催化剂的体系中一步水解缩合制备出笼型缩水甘油基倍半硅氧(G-POSS)。采用傅立叶变换红外光谱、核磁共振波谱及基质辅助激光解吸飞行时间质谱等手段对产物进行了分析和表征。结果表明,成功地合成了高纯度的笼型十缩水甘油基倍半硅氧(T10)。
Cage glydidyl polyhedral oligomeric silsesquioxanes(G-POSS) was prepared by one-step hydrolytic condensation from 3-(2,3-epoxypropoxy) propytrimethoxysilane(KH-560) in the system of isopropyl alcohol and tetramethylammonium hydroxide (TMAH). G-POSS was characterized using FTIR,1H-NMR and MALDI-TOF-MS. The results show that highly purified cage decaglycidyl polyhedral oligomeric silsesquioxanes is successfully prepared.

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采用羟基封端聚硅氧与甲氧基为原料在催化剂作用下通过缩聚反应制备了甲氧基封端聚硅氧,通过红外光谱,核磁共振仪对其化学结构进行表征,采用容量法研究了反应前后羟基含量的变化,考察了反应条件对该反应的影响规律.研究结果表明,最佳的反应条件:羟基与甲氧基摩尔比为1∶10,催化剂选用二月桂酸二丁基锡,用量为1.2%(质量百分数),反应温度为80℃,反应时间为6h.
Methoxy-terminated polysiloxane is prepared by polycondensation with hydroxy-terminated polysiloxane , methoxysilane and catalyst . The chemical structure of the product is characterized by IR and 1 H-NMR . The hydroxyl content before and after the reaction is studied by volumetric method .The effects of the reaction conditions on the reaction are investigated .The results show the optimum reaction conditions ,namely ,the mole ratio of hydroxy and methoxy is 1∶10 ,dibutyltin dilaurate is used as the catalyst with the amount 1 .2% (mass percentage) ,the reaction temperature is 80℃ , and the reaction time is 6h .
以α,ω-二羟基聚甲基三氟丙基硅氧为基胶、烃基三乙酰氧基为交联剂、气相法二氧化硅为补强填料、氧化铁红为耐热添加剂、γ-(2,3环氧丙氧)丙基三甲氧基(KH 560)为增粘剂、二月桂酸二丁基锡为催化剂,制成脱酸型单组分室温硫化(RTV-1)氟硅密封剂。探讨了基胶黏度、气相法二氧化硅用量、交联剂结构及用量对密封剂工艺性能和力学性能的影响。确定的较佳配方为100份黏度19 000 mPa·s的基胶、15份甲基三乙酰氧基、20份气相法二氧化硅、5份氧化铁红、2份KH 560、1份二月桂酸二丁基锡。按此配方得到的脱酸型RTV-1氟硅密封剂的工艺性能、常温力学性能、耐高温性能、耐油性能达到或超过国外同类产品的水平。
RTV-1 deacidified fluorosilicone sealants were prepared by using α,ω-bihydroxyl polymethyl trifluoropropyl siloxane as the raw rubber,and hydrocarbyltriacetoxysilane as the cross-linker,fumed silica as the reinforcing agent,red iron oxide as the heat resistant agent,glycidoxypropyltrimethoxysilane as the tackifi-er,and dibutytin dilaurate as the catalyst. The effects of the viscosity of fluorosilicone rubbers,the content of fumed silica,the structure and content of cross-linker on the mechanical and technical properties of the sealant were studied. The preferred formulation was that 100 parts of fluorosilicone with a viscosity of 19 000 mPa·s, 15 parts of methyltriacetoxysilane,20 parts of fumed silica,5 parts of red iron oxide,2 parts of glycidoxyprop-yltrimethoxysilane,and 1 part of dibutytin dilaurate. The obtained RTV-1 deacidified fluorosilicone sealants show good mechanical properties,high temperature resistance and good oil resistance,equal to or exceeding the simil
采用γ-氨丙基三乙氧基与尿素进行亲核取代反应,合成了γ-脲基丙基三乙氧基;通过对工艺条件的优化制备得到了纯度高达99%以上的产品并采用红外光谱及核磁进行了表征。
γ-Ureidopropyltriethoxysilane was synthesized by the nucleophilic substitution reaction ofγ-aminopropyltriethox-ysilane with urea;optimized the process conditions to obtain the product purity over 99%and characterized by IR and NMR spec-troscopy.

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以四甲基氢氧化铵(Me4 NOH)为催化剂,利用八甲基环四硅氧(D4)、四甲基四乙烯基环四硅氧(D4 V)、(3-缩水甘油醚丙基)-1,1,3,3-四甲基二硅氧(ETP)间的阴离子聚合法制得端环氧基聚甲基乙烯基硅氧(EPVMS).再利用EPVMS与含氢硅油间的硅氢化加成反应制得了新型交联网状端环氧基聚硅氧织物整理剂(CLPS).用红外光谱及核磁共振氢谱对其结构进行表征.结果表明,制备中EPVMS的环氧值和乙烯值控制为0.08 mmol · g -1及0.10 m mol · g -1较为适宜.红外光谱和核磁共振氢谱证实产物具有预期结构.随交联度增加,其疏水性增强.
Novel crosslinked polysiloxane with end-capped epoxy groups (CLPS ) as water-proofing agent for fabric was synthesized by hydrosilylation of polymethylhydrosiloxane (PHMS ) oligomer and an epoxy groups-terminated polyvinylmethylsiloxane (EPVMS ) , which was previously prepared via anionic ring-opening polymerization of octamethylcyclo-tetrasiloxane (D4 ) ,2 ,4 ,6 ,8-Tetramethyl-2 ,4 ,6 ,8-tetravinylcyclotetrasiloxane (D4 V ) ,and epoxy group-terminated polydimethylsiloxane (ETP) using tetramethylammonium hydrox-ide (Me4 NOH) as a catalyst .The resultants were characterized by Fourier transform infrared spectroscopy (FT-IR) ,nuclear magnetic resonance spectra (1 H NMR) ,and other instru-ments .FT-IR and NM R confirmed the structure of the resultants .Hydrophobicity of the CLPS was enhanced with augment of crosslinking degrees .

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将光敏性基团作为侧基或端基引入聚硅氧大分子中,在紫外光辐射下固化,充分结合了有机硅的高性能与光固化的高效.本文对近几年UV固化聚硅氧的合成方法,固化机理,表征手段及应用等的研究进行了综述.
Abstrect The photosensitive functional groups as branches or end segments,can be incorporated into polysiloxanes, and crosslinked under ultraviolet(UV). This research development combines the high efficiency of UV curing and the high performance of polysiloxane polymers. In this paper, an the recent progress of the research synthesis arts, curing mechanisms, characterization techniques and their applications are reviewed.

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