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双语推荐:铝硅合金

综述了低过共晶铝硅合金、中过共晶铝硅合金以及高过共晶铝硅合金缸体/缸套材料的研究及进展情况,详细叙述了缸体孔/缸套工作面激光合金化、激光刻蚀、珩磨加工、等离子体涂覆、化学腐蚀等加工技术,对存在的问题进行分析总结,并提出解决方法。
Research progress of low hypereutectic silicon,medium hypereutectic silicon or high hypereutectic silicon aluminium alloy cylinder/cylinder sleeve is summarized. The machining techniques for cylinder hole and working face of cylinder sleeve such as laser alloying,laser ablation,honing,plasma coating,chemical corrosion and so on are introduced in detail. The existing problems are analysed and the resolving methods are put forward.
合金熔炼的过程中分别加入RE(镧铈混合稀土)、Al-Ti-B和合金合金进行变质处理,研究不同变质剂对合金组织及力学性能的影响。结果表明,RE、Al-Ti-B和钪都是通过改变合金相的颗粒大小来改变合金的铸态组织,从而提高合金的综合力学性能。
In the process of melting, RE(lanthanum, cerium mixed rare earth), Al-Ti-B alloy and aluminum scandium alloy has been added respectively to study the effects of different modifiers on microstructure and mechanics properties of Al alloy. The results showed that RE, Al-Ti-B and Al-Sc alloys has been respectively changing the as-cast microstructure of Al alloy all by changing the particle size of silicon phase in alloy, thus improving the overall mechanics properties of the alloy.

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采用电磁搅拌结合定向凝固技术将过共晶铝硅合金中的初晶铝硅合金分离,并研究不同的杂质元素在铝硅体系中的分布特点。结果表明:杂质元素主要分布在铝硅合金以及铝硅合金和初晶的晶界中。同时,根据初晶富集区域不同位置含量的不同,初晶的形貌由鱼骨状变成板状和球状,并且随着样品中不同位置含量的增多,初晶中的杂质含量降低。样品底部杂质的含量约为10×10^-6,与原料冶金级中的杂质含量1248.47×10^-6相比,杂质的去除效果很好。
The primary silicon crystals and Al-Si alloy in hypereutectic Al-Si melt were separated by electromagnetic stirring and directional solidification. Additionally, the distribution feature of impurities in Al-Si system was verified. The results show that the impurities are mainly located in Al-Si alloy and the grain boundaries between the Al-Si alloy and primary silicon. Furthermore, the morphology of primary silicon changes from fish-bone like to plate like and spheroid due to the different Si contents. The amount of impurities decreases with the increasing of Si content in different positions of the sample. The amount of impurities in the bottom of the sample is approximately 10×10-6, which is obviously improved compared with the 1248.47×10-6 in metallurgical Si.

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以纯镁、纯、结晶、Al-50%Cu中间合金为原材料,采用电阻炉熔化重力浇注法制备不同成分的过共晶铝硅合金。采用正交试验方法,探讨合金固溶时效处理后不同含量的15%~21%Si、1.5%~2.0%Cu、0.3%~0.7%Mg合金元素对过共晶铝硅合金硬度的影响;利用金相显微镜观察不同元素含量的过共晶铝硅合金的组织,用X线分析其相组成,用磨损试验机测试质量损失。结果表明:最佳配比为1.5%Cu、0.7%Mg、21%Si,其相组成为α-Al基体、初晶相和共晶相以及Mg2Si和Al2Cu相,布氏硬度达到132HB,耐磨损性能较高但冲击韧性下降。
With pure aluminum,pure magnesium crystal,silicon,intermediate alloy (Al - 50% Cu) as raw material, hypereutectic Al-Si alloys were prepared by the method of resistance furnace melting and gravity casting preparation. Using orthogonal test method,the effect of different content alloying elements of 15%to 21%Si,1.5%to 2.0%Cu,0.3%to 0.7%Mg on hardness of hypereutectic aluminum-silicon alloy treated by solid solution aging was studied. Metallographic microscope was used for microstructure observation,X-ray analysis for the phase composition,and abrasion tester for weight loss. Experimental results show that the optimun ratio for the content of Cu,Mg,Si is 1.8%,0.3%,21%,respectively. The phase composition consists of alpha-Al matrix phase and primary silicon and eutectic silicon phase and phase Mg2Si and Al2Cu. Brinell hardness is 132HB,and wear resistance is higher,while impact toughness drops.

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采用液-液混合受控扩散凝固技术(CDS)制备过共晶Al-20%Si合金,研究高硅合金温度对目标合金组织中初生的影响及混合过程中初生细化的热力学条件。结果表明:采用液-液混合制备过共晶铝硅合金,可以细化初生,初生平均尺寸可达到37μm;但随着高硅合金温度的升高,初生的平均尺寸增加,板条状和五瓣星状初生也增多,当高温度超过790℃时,初生细化效果丧失。分析得出,只有当混合前两种合金吉布斯自由能的加权平均值小于混合后目标合金在液相线的吉布斯自由能(liquidusfinal,m G=-39.336 6 kJ)时,初生才能得到明显的细化。
The hypereutectic Al-20%Si alloy was fabricated by liquid-liquid mixing of controlled diffusion solidification (CDS), and the effect of temperature of high silicon alloy on the microstructure of primary silicon phase and thermodynamic condition of primary silicon refinement in the mixing process were studied. The results show that the primary silicon can be refined obviously and the size of the primary silicon can reach 37 μm in the preparation of hypereutectic Al-20%Si alloy fabricated by liquid-liquid mixing. When the temperature of high silicon alloy increases, the primary phase size increases. When the high silicon temperature is over 790 ℃, the refinement effect of primary silicon is lost. Additionally, when the Gibbs free energy of the liquids prior to mixing is less than the Gibbs free energy of the resultant liquid at its liquidus temperature ( final,liquidusmG =-39.336 6 kJ), the primary silicon phase will be refined obviously.

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利用电化学测试、扫描电镜和能谱分析等方法,对不同 Sr 元素添加量合金在1 M HCl 溶液中电化学腐蚀表面形貌的变化以及开路电位和动电位极化曲线进行了研究。结果表明,由于 Cl-的侵蚀作用,铝硅合金在1 M HCl中发生点蚀破坏,随着腐蚀时间的延长,未添加 Sr 元素合金的点蚀扩展并形成腐蚀缝隙,而经0.04%Sr变质的合金则保持点蚀的纵向加深与扩展。微量 Sr 元素的加入,一方面,促使铝硅合金中片状初生转变为纤维状共晶,使开路电位负移;另一方面,促进氧化,形成钝化膜,减缓Cl-侵蚀作用,增强合金耐点蚀性。在0.1 M HCl溶液中,Sr元素的添加量为0.1%时,ZL102合金的耐腐蚀性最佳。
The changes of the surface morphology by electrochemical corrosion processing,open circuit potential,potentiody-namic polarization cure were investigated on different amount Sr addition with electrochemical analysis,scanning electron microscopy and EDS.The result indicated that pitting corrosion occurred for Al-Si alloy as the corrosion of Cl-.Pitting corrosion of no Sr addi-tion alloy deepened into corrosion crevice while the 0.04% Sr addition alloy developed into longitudinal deepening and spreading of pitting corrosion with extension of corrosion time.The minor addition of Sr varied the morphology of eutectic Si from the flake-like primary silicon to fibrous eutectic Si,reduced open circuit potential on the one hand and oxidized Al to passive film,weakened the effect of Cl-on pitting,reduced pitting corrosion damage on the other hand.The best Sr addition amount was 0.1% in 0.1M HCl solution.

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通过不同温度和时间的固溶制度研究了固溶处理工艺对改良铸造铝硅合金(0.35%Mg,7.0%Si,0.2%Ni,2.0%Cu,0.8%RE,0.2%Mn,0.1%V,其余为)组织和性能的影响。实验结果表明,在495℃×5h进行固溶处理时,改良铸造铝硅合金具有最好的综合力学性能:Rm=239MPa,硬度=103HBS,A=6.24%;改良铸造铝硅合金于495℃×5h固溶淬火析出富含Si、Cu、Ni以及RE元素的Si、AlCu、Al6Cu3Ni、AlxCuCe相。这些相的存在,有利于提高合金的力学性能和高温性能。合金经过热处理后以韧性断裂为主要方式并伴有准解理面现象,拉伸断口微观形貌主要表现为韧窝断口特征,有些存在少量撕裂棱。
By aid of solution system with different temperature and time, effect of solution treatment process on the microstructure and mechanical properties of modified aluminium silicon casting alloy(0.35% Mg,7.0% Si,0.2% Ni,2.0% Cu,0.8% RE,0.2% Mn, 0.1% V,balance is Al)was studied. The results show that,at 495℃×5h for solution treatment,modified aluminium silicon casting alloy has the best comprehensive mechanical properties:б=239MPa,HBS=103HBS,β=6.24%;modified aluminium silicon casting alloy at 495℃×5h after solution quench had Si,AlCu,Al6Cu3Ni,AlxCuCe phases containing rich Si,Cu,Ni and RE elements. These phases were helpful to improve the mechanical properties and high temperature performance of alloy. Ductile fracture for alloy after heat treatment is the main way and is accompanied by the quasi cleavage phenomenon. The tensile fracture morphology is mainly dimple fracture characteristics, some of the presence of a small amount of tear ridges.

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采用稀土Nd对3种不同Si含量Al-(18、22、26)Si的过共晶铝硅合金进行变质处理,研究Nd对合金的铸态组织以及摩擦磨损性能的影响。结果表明:随着含量的提高,组织中初晶含量变多,尺寸增大;加入0.5%的Nd使组织中的初晶得到明显细化,合金组织中较大的板状和多面体状的初晶变为细小的多面体状,而且其尖锐的棱角变得圆滑;随着含量的增加,合金的耐磨性得到提高,合金的磨损率分别由变质前的1.4573、1.1181、0.9662m3/(N·m)下降为1.284、0.853、0.785m3/(N·m)。
Hypereutectic Al-(18,22,26)Si alloys were prepared by modification treatment of adding Nd,and the influence of Nd on cast microstructure and wear properties of Al-(18,22,26)Si was studied. The results show that the amount and size of primary silicon become large with the increase of silicon content;when Nd content of Al-(18,22,26)Si is 0.5%,primary silicon is obviously refined and transformed from larger plate and polyhedron into small polyhedron,the sharp edge becomes more smooth. Meanwhile,the wear resistance of the alloy is improved with the addition of silicon,the wear rate of alloy decreases to 1.284,0.853,0.785 m3/(N·m),compared with 1.457 3,1.118 1,0.966 2 m3/(N·m)before modification.

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通过机械合金化结合热压致密化的工艺制备Al-30Si、Al-40Si、Al-50Si 3种成分的高硅铝合金,采用金相、SEM、EDS、压缩实验、摩擦磨损试验等对合金的组织、抗压强度及摩擦磨损性能等进行研究。结果表明:合金显微组织中呈现Al相富集区、Si相富集区和铝硅混合区3种区域,且合金中Si颗粒细小,没有明显长大的现象。合金的抗压强度随Si含量的增加先升高后降低。Al-40Si合金具有最佳的耐磨性和减摩性,其磨损机理主要是磨粒磨损和氧化磨损。除磨粒磨损外,Al-30Si合金磨损初期存在粘着磨损,后期则以氧化磨损为主,而Al-50Si则存在较严重的剥层磨损。
Three kinds of high-silicon aluminum alloys (Al-30Si, Al-40Si and Al-50Si) were fabricated by mechanical alloying and hot pressing. The microstructures, compressive strengths and wear-friction properties of the alloys were investigated by metalloscope, scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), compression tests and friction-wear tests. The results show that the microstructure of the alloys contains Al-rich region, Si-rich region and Al-Si mixed region, and the ultrafine Si particles in the matrix do not grow up obviously after the hot pressing process. The compressive strength of the alloys increases firstly and then decreases with increasing Si content. Al-40Si has the lowest mass loss and friction coefficient, its wear mechanism is mainly abrasive wear and oxidation wear. Besides abrasive wear, the wear mechanism of Al-30Si alloy contents adhesive wear at the beginning and then following oxidative wear, while Al-50Si alloy contents distinctly desquamat

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基于多元、少量合金化的思路,根据不同合金元素的不同作用,对目前大量使用的系铸造铝合金进行了再开发,创新发明了一种全新的铸造铝合金。其力学性能相比国内外同类材料有了明显提高,是扩大使用铸造铝合金制造轴流风机叶片的新途径。
Based on thought of multivariate, a small amount of alloying train, according to the different function of different alloying elements, and the current use of aluminum alloy casting-silicon is further developed, and a new casting aluminum alloy is invented. Their mechanical property compared with similar material at home and abroad is obviously improved, is a new way of expanding the use of casting aluminum alloy to manufacture axial flow fan blade.

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