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双语推荐:传质

针对Lee相变传质方程中传质系数主要依靠经验取值的问题,本文尝试提出一种确定传质系数的方法,给出了评价传质系数合理性的2个指标——潜热份额(潜热换热量占总换热量的份额)和饱和温差(流体温度与饱和温度的差值),建立了稳态分析模型,通过理论推导,得出了潜热份额和饱和温差的理论表达式,据此分析了传质系数对模拟结果的影响,已有特定条件下的理论解验证了本文分析结果的正确性.分析结果表明传质系数越大,计算精度越高.基于分析结果解释了不同文献对该系数取值差异很大的原因,并给出了传质系数的通用取值方法,最后推荐了常见工况模拟中传质系数的合理取值范围.
To solve the problem that the mass transfer coefficient in Lee''s equation need to be obtained depending on the experience, a method was proposed, and two indexes evaluating the rationality of the mass transfer coefficient?latent heat share ( the share of latent heat flux in total heat flux) and saturation temperature difference ( difference between fluid temperature and saturation temperature) were presented. A steady state model was established to analyze this problem and the expression of latent heat share and saturation temperature difference were obtained by the theoretical guidance. By the expression, the effect of mass transfer coefficient on the simulation was analyzed. The analysis result was validated by the existing theoretical result in particular cases. The results show that the calculation accuracy increases with the increase of the coefficient. Based on these results, the reason for large difference of the coefficient value in different literatures was explaine

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从理论上分析了溶液除湿过程中传质过程和传热过程之间的耦合关系,建立了相应的数学模型,并对实际的溶液除湿过程进行了数值模拟。结果表明:传质过程对传热过程的影响主要体现在两方面:一是传质通量携带的焓对传热过程的影响,二是水蒸气变成水释放汽化潜热对传热过程的影响,其中汽化潜热的影响较大。而传热过程对传质过程的影响主要体现在温度对传质系数的影响。
Coupling relationship between the mass transfer process and heat transfer processes in liquid desiccant dehumidifica -tion process is analyzed theoretically , the physical and mathematical model is developed , and simulates the actual liquid desic-cant dehumidification process .The result shows that:the influence of mass transfer process to the heat transfer process is mainly embodied in two aspects:first, the enthalpy carried by the mass flux impact on the heat transfer process , the second is the water vapor turns into water release of latent heat of vaporization influence on the heat transfer process , between them, the latent heat of vaporization is affects obviously .The influence of heat transfer process to the mass transfer process is mainly embodied in temper -ature.

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核电厂蒸汽发生器传热管的降质将影响到核电厂一回路边界的完整性。通过对蒸汽发生器传热管的降质模式进行分析,并对在役传热管无损检测技术应用以及寿命预测的介绍,从而针对产生的传热管降质的原因,采取相应的防护措施,确保蒸汽发生器传热管的安全运行。
Degradation of tube of steam generator will affect the integrity of primary loop ,after analysis the degradation model of tube ,and introduction of nondestructive testing technology application for in -serv-ice tube and steam generator tube life estimates ,take the corresponding protective measures per the cause of degradation of the tube ,to ensure safe operation of the tube of the steam .

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气液传质广泛存在于气体分离等化工过程中,强化气液传质有助于实现高效率低能耗的生产。在气液两相体系中加入第三分散相固体颗粒是强化气液传质的一个重要方法。该文对微米颗粒及纳米颗粒强化气液传质的实验和理论研究成果进行了总结与比较,对目前的研究中存在的问题进行了分析。在传统气液传质理论的基础上,阐述了3种被学者广泛认可的颗粒强化气液传质的机制,简单介绍了几个可以微观上解释颗粒强化气液传质现象的均相和非均相模型,比较了它们的使用范围和准确度。最后,在对已有文献综述的基础上对纳米颗粒强化气液传质的研究方向进行了展望。
Gas-liquid mass transfer is widespread in chemical industrial processes like gas separation. Enhancing gas-liquid mass transfer can help achieve production process with high efficiency and low energy consumption. It is an effective method to enhance gas-liquid mass transfer by adding the third dispersed solid particles. A review and comparison of the experimental and theoretical research results on gas-liquid mass transfer in the presence of fine particles were presented and existing problems were analyzed. Based on the traditional gas-liquid mass transfer theories, three widely accepted mechanisms explaining gas-liquid mass transfer enhancement caused by fine particles were introduced. Several homogenous and heterogeneous models developed for micro-explanation of the enhancement effect were discussed briefly, with their application scope and accuracy compared. Finally, the study directions in the field of gas-liquid mass transfer with nanoparticles were proposed based on the overview.

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基于旋转填充床流体流动的可视化结果,建立了超重力旋转填充床气液传质过程的数学模型,模拟氮气解吸水中溶解氧的传质过程。模拟结果表明,缩短液相停留时间、提高液相扩散系数都能增大液相传质分系数kL;总体积传质系数KLa随超重力因子的增加而增大、随温度的上升而增大、随气相流率的增加略有下降、随液相流率的增加明显增大;空腔区传质贡献率随空腔区的增大而增大,随超重力因子的增大而减小;且短暂的停留时间是超重力旋转填充床对传质过程强化的本质原因。模型较好地符合文献的实验数据,误差在±16%以内。
A mathematical model for gas-liquid interphase mass transfer was established based on the visual study of fluid flow in a rotating packed bed (RPB). The effects of model parameters on liquid mass transfer coefficient kL, as well as the effect of operation parameters on overall volumetric mass transfer coefficientKLa in gas-liquid mass transfer process of water deoxygenation by a nitrogen stream were studiedvia numerical simulations with the mathematical model. Simulation results indicated thatkL increased with decreasing liquid residence time and increasing liquid molecular diffusivity.KLa increased with increasing higee (high gravity) factor, temperature and liquid flow rate but influenced hardly by pressure, and decreased slightly with increasing gas flow rate. Additionally, the mass transfer contribution of cavity zone diminished with increasing higee factor, as well as decreasing cavity zone volume. According to numerical simulation results, the nature of process intensification fo

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对低界面张力体系正丁醇-丁二酸-水在往复振动筛板塔中的萃取性能进行研究,体系中水为萃取剂,萃取正丁醇中的丁二酸。实验考察了两相流速、相比、传质方向和筛板振动速率对流体力学性能和传质性能的影响,并且与相同操作条件下固定筛板萃取塔的性能作对比。结果表明,筛板振动速率不高于3.5 cm/s的情况下体系没有发生乳化现象,相比增大到2.8时接近液泛点,实验稳定性较差。流速和相比增大能够获得更好的液滴分布和更大的体积传质系数,但增大的幅度要综合考虑设备的最大通量和两相在塔内的停留时间。分散相到连续相的传质方向传质相界面积大,更有利于提高传质效率。相同操作条件下,连续相中的轴向混合远大于分散相的轴向混合。与固定筛板塔的萃取性能相比,振动筛板改善液滴分布、增大处理能力和强化传质的作用都很明显。
This paper studied the extraction performance of low interfacial tension system n-butanol-succinic acid-water (BSW) in a Reciprocating Plate Extraction Column (RPEC). Water as the solvent, extracted succinic acid from n-butanol phase. The experiment investigated the effects of flow rate,phase ratio, mass transfer direction and reciprocating rate upon the hydrodynamic and mass transfer performance. The results of extraction using stable sieve plate were compared. The results indicated that the reciprocating rate of plates should not be higher than 3.5cm/s to avoid emulsion. When phase ratio was 2.8,the operation approached the flooding point,and the experiment was not stable. The distribution of drops was better and the volumetric mass transfer coefficient was greater under the condition of higher flow rates and larger phase ratio. However, the range of increase was limited by the maximum throughput and the residence time of two phases. Due to its larger interface area, mass t

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利用超声场鼓泡塔和双电导探针气泡特征参数测量仪实时测定了加入不同种类和不同浓度添加剂前后鼓泡塔内氨气气含率与传质系数变化规律。实验结果表明:无添加剂时,超声频率为20-50-100 kHz组合,功率100 W时,鼓泡塔内气含率比无超声作用时增加了37%~74%,传质系数增大了39%~61%;气含率和传质系数随加入正辛醇浓度的增大呈现逐渐增长的趋势,当正辛醇浓度超过1.0%(V)时,气含率和传质系数趋于稳定;超声频率为20-50-100 kHz组合,超声功率100 W,正辛醇浓度为1.0%时鼓泡塔内气含率比无添加剂加入时增加了20%,传质系数增大了16%,可见超声场与添加剂协同作用有利强化气液相间分布、提高传质效果。
This study deals with using a bubble feature measuring system named duplex conductivity probe to investigate the effects of kinds and concentrations of additives on the gas holdup and mass transfer coefficient in a bubble column with ultrasonic radiation of one frequency or multi-frequency. The results show that, in reverberating ultrasonic field of multi-frequency combination of 20-50-100 kHz and power of 100 W, the gas holdup of the without additives system increases 37%~74%, and at the same time, the mass transfer coefficient of the system increases 39%~61%. The gas holdup and the mass transfer coefficient of the system increase with increasing the concentration of octanol additive when the concentration is below 1.0%(V), and then they almost keep constant as the octanol additive concentration is increased beyond 1.0%. In reverberating ultrasonic field of multi-frequency combination of 20-50-100 kHz and power of 100 W, when the octanol additive concentration is 1.0%, the gas holdup

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中空纤维透析器广泛应用于终末期肾病的血液透析治疗,对全球的肾病患者有着重要作用,然而关于透析器溶质传递方面的研究却很少。本文根据质量守恒定律和双膜理论建立了一个中空纤维透析膜传质模型,使用中小分子代表物质对三种常用膜材料进行测试,并使用该传质模型计算总传质系数和纤维膜的扩散系数,分析纤维膜传质性能与纤维膜材料/结构特性之间的相互关系,为中空纤维膜制备过程中的材料选择、结构优化设计等提出了参考性建议。
Hol ow ifber dialyzer is widely applied in the end-stage renal disease in hemo-dialysis therapy. It plays an important role in kidney disease patients in the world. However, there is lit le research of solute transfer in dialyzer. This paper builds a mass-transfer model of dialysis hol ow ifber membrane, based on mass-conservation theory and double-membrane theory. Three common membrane materials are tested and calculated with the mass transfer model with represent solutes. With analysis of relationship between mass-transfer performance and the structural characteristics of membrane, referential suggestions for material selection and structural design in manufacture of hol ow ifber membrane are put forward.

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在水产养殖池塘中微孔曝气充氧系统日益受到关注,为了探究微气泡-水界面与水表面湍动对氧传质的贡献,在不同曝气流量、不同淹没水深条件下进行了水体底部微孔曝气增氧试验。基于氧体积传质理论,采用美国土木工程协会推荐的计算模型和两区氧传质模型进行耦合求解,计算得到了水体底部微孔曝气增氧过程中气泡-水界面和水表面湍动扩散氧体积传质速率。对温度修正后的体积传质速率进行分析,结果表明,在一定的淹没水深下,气泡-水界面和水表面湍动扩散氧体积传质速率均与曝气流量成正比;而在一定的流量下,气泡-水界面和水表面湍动扩散氧体积传质速率与水深成反比。针对于浅型养殖池塘,随着曝气管淹没水深的增加,虽然水表面传质的贡献率有所下降,但是其贡献仍然很大,占到了80%以上。结合微孔曝气式增氧系统具有能耗较低、安装简单等优点,采用微孔曝气式增氧系统对浅型水域增氧和湍动混合具有较大优势,值得推广采用。
Micro porous aeration systems for increasing dissolved oxygen concentration in an aquaculture pond are receiving more and more attention. In order to explore the contribution of a micro bubble-water interface and the turbulent water surface to oxygen mass transfer, after placing a disc which was made of a curled micro porous diffuser tube in the middle bottom of an experimental pond, a series of re-oxygenation experiments were conducted under the conditions of different aeration flow and submerged water depth. Based on the theory of oxygen volume mass transfer, the calculation model recommended by the American Society of Civil Engineering (ASCE) was coupled with the Two-Zone oxygen transfer model, and then the two kinds of oxygen volume mass transfer coefficients across the micro bubble-water interface and across the turbulent water surface during the re-oxygenation process in the bottom of the experimental pond were calculated. After water temperature correction, the values of oxygen

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研究应用GOTHIC8.0程序分析AP1000核电厂非能动安全壳冷却系统(PCS)传热传质过程,通过理论计算和程序分析两种方式对分析结果进行比较和评价。研究结果表明:GOTHIC8.0程序的DLM‐FM模型适用于模拟安全壳内蒸汽在安全壳内壁面的冷凝传热传质过程,Film模型适用于模拟安全壳外水膜的蒸发传热传质过程。GOT HIC8.0程序可用于分析AP1000核电厂 PCS传热传质过程,为AP1000核电厂在设计基准事故(DBA)下安全壳响应分析提供了另一种可行的工具。
The GOTHIC8.0 code was used to analyze heat and mass transfer process for passive containment cooling system (PCS ) of AP1000 NPP ,and the analysis results were compared and evaluated by theoretical calculation and code analysis .The results show that the DLM‐FM model is adopted to model the condensation process on the inside wall of containment ,the Film model is used to model the evaporation process on the outside wall film of containment .It shows that GOTHIC8.0 code is applicable to analyze heat and mass transfer process for PCS of AP1000 NPP and it is possible to be another tool to analysis AP1000 NPP containment response during DBA .

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