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双语推荐:树脂固砂液

疏松岩油藏开发过程中出严重,防技术成为维持疏松岩油藏油井长期正常生产的主要措施之一。针对海上疏松岩稠油油藏开采出井防问题,室内初步研制了新型一体化树脂固砂液体系以提高体胶结强度。室内研究表明,新型一体化固砂液体系具有良好的胶结化性能,扩孔后渗透率保留率高,低温结性能强,结质量好,抗腐蚀性能强,能够满足油田现场的固砂作业。
Because sand flowed seriously in the process of the development of unconsolidated sand reservoir,sand control technique became one of the main measures to maintain the long-term normal production of the well in such reservoir. Laboratory preliminary developed the new integrative gel type resin system in order to improve the curing strength of sand body in view of the sand control of sandy well in unconsolidated sand heavy reservoir at sea. Such system can meet the sand consolidation work of oil field which showed many advantages in the laboratory study such as good performance of cementation solidifying,high permeability retention after borehole enlargement,strong consolidation at low temperature,consolidation of good quality,intense corrosion resistance and so on.

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树脂型压井是一种无体,体系中自由水被高吸水性树脂束缚而呈颗粒状冻胶状态,具有良好的储层保护效果。压井中冻胶粒径大,有一定的强度,可变形,易流动,在压力作用下,冻胶颗粒在储层表面形成封堵层,阻止体向地层中渗透。室内研究表明,树脂型压井具有较好的储层保护功能。在现场施工中,树脂型压井性能稳定,滤失量低,携性强,与地层水配伍性良好。在低压井的应用中没有发生漏失,修井后返排时间短,返排含水率低,进入正常生产流程后,产量提高,有利于修井后产能的恢复。
Resin type well control fluid is a solid-free liquid ,and the liquid looks like jelly be-cause the free water of system is trapped by high absorbent resin ,so that it has good reservoir protection .The jelly has big particle size and a certain strength ,as well it is deformable and easy to flow ,so it covers the reserve surface and prevents water leakage .The laboratory study dem-onstrates that the well control fluid has good reserve protection ability .In site construction ,the well control fluid has stable performance ,low filter loss ,strong carry capacity ,and good com-patibility with formation water .The application of low pressure well shows it is useful in preven-ting leakage and reducing backflow time .The moisture content of outlet liquid is low ,and the liquid production increases after entering the normal production process .It is advantageous to the productivity recovery .

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研究陈旧性树脂表面形态学改变以及对新旧树脂间粘结强度的影响。方法:制备Z350纳米树脂样本10例,浸泡于37℃蒸馏水中1个月后,使用同种树脂完成样本制备,用体视显微镜和扫描电镜对样本的表面及切面进行形态学观察。万能材料试验机上测定材料的微拉伸强度。结果:陈旧性树脂表面纳米填料颗粒从树脂基质中消失,且新旧树脂间存在间隙,陈旧性树脂修复后微拉伸强度明显降低。结论:新旧树脂界面是导致树脂粘结强度下降的薄弱区。
10.3969/j.issn.1674-8603.2013.02.009

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通过工艺条件的优化和催化剂的选型,在淤浆法聚乙烯装置上开发了氯化聚乙烯(CPE)专用高密度聚乙烯(HDPE)树脂。该CPE专用HDPE树脂与同类树脂的相对分子质量及其分布相当,密度介于国产树脂A和进口树脂B之间;结晶温度接近进口树脂A,但熔融温度及热焓较进口树脂A略高;熔体流动速率和堆密度与进口树脂A相差不大;大颗粒及细粉含量都少于进口树脂,且粒径分布更集中;孔径、孔容以及比表面积与进口树脂A接近。采用该CPE专用HDPE树脂生产的制品各项性能均达到了指标要求。
Special?high?density?polyethylene?(HDPE)?resin?for?producing?chlorinated?polyethylene?(CPE)?was?developed?by?optimizing?polymerization?parameters?and?selecting?proper?catalyst?in?a?slurry?polyethylene?plant.?The?resin?had?similar?relative?molecular?mass?and?its?distribution?to?those?products?of?the?same?kind.?And?the?density?of?the?resin?was?between?those?of?the?domestic?resin?A?and?imported?resin?B.?The?resin''s?crystallization?temperature?was?close?to?that?of?the?imported?resin?A,?while?its?melt?temperature?and?enthalpy?were?slightly?higher?than?those?of?the?imported?resin?A.?The?melt?flow?rate?and?bulk?density?of?the?resin?were?similar?to?those?of?the?imported?resin?A.?The?resin''s?quantity?of?large?particles?and?fine?powder?were?less?than?those?of?the?imported?resins,?and?its?particle?diameter?distribution?was?narrower?than?those?of?the?imported?resins.?The?pore?diameter,?pore?volume?and?the?specific?surface?area?of?the?resin?were?close?to?those?of?the?imported?resin?A.?T

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综述了树脂污染和树脂吸收有机物的机理,并对污染树脂常用的几种复苏方法作了简要介绍和比较。自然界中甲基化速度加快会使水质恶化,富里酸离解产生的离子与树脂中甲基污染物反应可以去除树脂中的有机污染物。离子型树脂吸附有机物能力低于OH-型树脂,用Cl-型树脂作为有机物清除剂是因为洗脱容易,但由于吸附能力低,有机物容易漏过,对除盐不利。经过对几种复苏方法的比较,有机溶剂法是效果最好的复苏方法,复苏后,可以大大提高树脂的理化性能。
Discussed the mechanism of resin pollution and the mechanism of resin absorbing the organics, introduced and compared several commonly used resuscitation methods. Speeding up the imethylation will lead to the deterioration of groundwater quality. The reaction between the ion from the dissociation of the fulvic acid methyl and the groups pollutant can remove the organic pollutant in resin. The adsorption capacity of ionic resin is inferior to OH- resin. The elution is easier to use Cl- resin as organic matter scavenger, but the desalting is difficult because organic matter is left off easily. The organic solvent is an effective recovery method, because it can improve the physicochemical property of the resin greatly.

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综述了微波辐射下五种淀粉接枝共聚高吸水树脂的制备研究进展,包括淀粉接枝丙烯腈类高吸水树脂、淀粉接枝丙烯酸类高吸水树脂、淀粉接枝多元单体类高吸水树脂、淀粉系列互穿网络高吸水树脂、无机复合淀粉接枝高吸水树脂等;指出了微波辐射制备淀粉接枝共聚高吸水树脂的研究中,几个需要加强的研究方向:加强理论研究与实践研究的相互促进,开发新型无机矿物复合淀粉接枝共聚高吸水树脂等。
The advances in preparation of main five categories of starch graft copolymer series super-absorbent resin by microwave irradiation including starch grafting acrylonitrile, starch grafting acrylic acid, starch grafting multi-monomers,interpenetrating polymer network structure starch grafting copolymers, and complex type starch grafting copolymers were thoroughly reviewed. Some trends needs to be strengthened in preparation of starch graft copolymer series super-absorbent resin were also emphasized,such as strengthen the mutual promotion of theory and practice,developing of new inorganic mineral composite starch grafting copolymer super-absorbent resin.

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用丙烯酸对PAEN脂进行改性,以期替代传统PAE树脂作为纸张的增强剂。探讨了在PAE树脂中引入丙烯酸的改性工艺及其应用,同时对改性PAE树脂的增强性能进行了研究。研究结果表明:在PAE树脂成品中引A.9%的丙烯酸为最佳改性工艺,在此工艺条件下制备的改性PAE树脂对纸张的增强效果最佳;当改性PAE树脂用量为0.6%时,与使用1.0%传统PAE树脂的增强作用效果基本相当;另外在PAE树脂成品中引入丙烯酸,有利于PAE树脂成本的降低。研究成果对改性PAE树脂的研究、开发及应用具有较强的参考价值。
PAE resin was modified with acrylic resin, instead of traditional PAE resin as paper strengthening agent. The improvement process and its application for the combination of acrylic with PAE resin were discussed, as well as the performance of the modified PAE resin as paper strengthening agent. The results show that adding amount of 9%acrylic into the PAE resin can reach to the best strengthening effect; when dosage of modified PAE resin is 0.6%, the strengthening effect is equal to the traditional PAE resin at the dosage of 1.0%; in addition, adding acrylic into PAE resin can reduce the cost of the PAE resin. The results will provide as a reference on the research, development and application of modified PAE resin.

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考察妥尔油改性酚醛补强树脂SL-2101和腰果油改性酚醛补强树脂SL-2201对全钢载重子午线轮胎三角胶性能的影响。结果表明:与补强树脂SL-2101相比,补强树脂2201对胶料的补强性能好;随着2种补强树脂用量增大,胶料物理性能提高;采用补强树脂SL-2201替代补强树脂SL-2101,需适当调整硫化体系。
In this study, tall oil modified phenolic resin SL-2101 and cashew nut oil modified phenolic resin SL-2201 were applied in the bead ifller of TBR tire. The experimental results showed that the properties of the compound were improved with increasing the content of either phenolic resin. Compared with SL-2101, the properties of the compound with SL-2201 were better. However, the curing system needed proper adjustment when SL-2201 was applied to replace SL-2101.
以4,4’-二氨基二苯甲烷(AG80)为基体树脂,以4,4’-二氨基二苯砜(DDS)为化剂,制备了树脂体系并进行改性研究。对树脂粘度、凝胶时间、DSC及浇注体力学性能等方面进行了测试。结果表明,通过树脂改性可以增加树脂体系的粘度,减少树脂体系的凝胶时间,树脂体系浇注体的力学性能,随着改性填料的加入呈现出先增强后减小的规律。
The key performance of modified epoxy resin prepared from epoxy resin (4,4 ’-diamino diphenyl methane),silicon carbide,diatomite and curing agent (4,4’-diamino diphenyl sulfone)was researched.Besides viscosity,gel time of resin and mechanical properties of casting body was tested.Experiment showed that the viscosity of the modified resin was higher than the original one,and the gel time was much less.And with the addition of packing the mechanical properties of the modified resin enhanced firstly then decreased.

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采用悬浮聚合法制备了球形苯类吸收树脂,研究了交联剂用量与树脂的吸收倍率、交联密度和凝胶分数之间的关系,探讨了交联结构对树脂吸收和释放动力学的影响,并采用扫描电镜考察了树脂的微观形貌。结果表明:随着交联剂用量的增加,吸收树脂的凝胶分数和交联密度不断增大,吸收倍率出现峰值;随着交联密度的提高,吸收树脂对甲苯的吸收速率和释放速率均减慢,吸收动力学常数与释放扩散系数都不断降低;树脂对甲苯的吸收动力学过程符合准一级动力学方程;得出了形式简洁的吸收树脂释放动力学方程,能够很好地描述吸收树脂释放甲苯的动力学行为;吸收树脂的交联结构稳定,再生重复使用10次以后树脂微球的大小、形貌和吸收倍率均无明显变化。
Spherical absorbent resins for benzene series were synthesized by suspension polymerization. The dependence of absorbency, crosslinking density and gel fraction of resins on crosslinker dosage was studied. The effects of crosslinking structure on absorption kinetics and release kinetics were investigated. Scanning electron microscope was used to observe the morphology of the resins. Gel fraction and crosslinking density kept increasing while a peak absorbency was observed with increasing crosslinker dosage. With the increase of crosslinking density, absorption rate and release rate of the resin for toluene reduced gradually, and absorption kinetic constant and diffusion coefficient decreased. Absorption kinetics of the resin for toluene fitted the quasi first order equation. A simple release kinetics equation was obtained, by which the release behavior could be well described. Crosslinking structure of the resin was stable. The size, morphology and absorbency of the spherical

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