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双语推荐:氯化物熔盐

基于原油蒸馏过程的操作条件,分析了在不同处理阶段原油中无机氯化物及有机氯化物的存在形态。参考了文献中有关原油及馏分油中氯化物的浓度数据,在假设水蒸气及氯化物水解相关产物浓度的情况下,对原油蒸馏过程中无机氯化物及有机氯化物的水解反应进行了热力学分析,并判断了无机氯化物及有机氯化物发生水解的可能性,最终得到了原油蒸馏过程中不同加工阶段腐蚀性组分HCl的主要来源,可为原油蒸馏过程中氯化物转移和转化规律的探索及氯化物危害的防治提供指导。
T he existing forms of inorganic and organic chlorides in crude oil during the different stages of crude oil distillation process were investigated based on the operation conditions of crude oil distillation process . Referred to the chlorides concentration data in relative crude oil and distillates , the thermodynamic analysis on hydrolysis of inorganic and organic chlorides in the distillation process of crude oil were completed . On the specified concentration of steam and products of chloride hydrolysis , the hydrolytic possibility of inorganic and organic chlorides in crude oil was estimated . Furthermore , the origin of the corrosive components‐‐‐HCl in the distillation process of crude oil was revealed ,which could provide guidance to the study of transfer and conversion of chlorides and the prevention hazard from HCl in crude oil distillation process .

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原油中的氯化物在原油加工过程中造成设备腐蚀、管道阻塞及催化剂中毒等。文中对国内外原油中氯化物的脱除技术进行了综述,现有的工艺对无机氯化物的脱除效果较好,但对有机氯化物的脱除效果不佳,开发新的脱氯技术是原油加工今后的研究方向。
Hazards of chlorides in crude oil in processing were described,which include equipment corrosion,pipe clogging and catalyst poisoning. The development and research on chlorides at home and abroad were reviewed. The advantages and disadvantages chloride removal technologies, such as electric desalting and dehydration processes, adsorption process and catalytic process,were discussed. The inorganic chloride removal effect of the existing technology is better,but it is ineffective for removing organic chlorides,so the development of novel dechlorination technology is the research direction in the future.

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本文通过对辽东湾北部和东、西两侧滨海地区108个地下水井的监测数据进行分析,得出:(1)辽东湾海水入侵严重地区主要分布在辽东湾北部淤泥质海岸,其分布特点是严重海水入侵区、轻度海水入侵区由岸向陆呈带状分布;东西两侧以砂砾质海岸为主,局部地区海水入侵较重,大部分地区海水入侵较轻;(2)辽东湾地下水化学类型可分为五种类型,其分布特点是由岸向陆呈带状分布,规律明显,反映了海水入侵分布特征。氯化物型一般分布在微咸水至咸水区,重碳酸盐氯化物型或氯化物重碳酸型、重碳酸盐氯化物硫酸型或氯化物重碳酸硫酸型分布在微咸水向淡水过渡区,硫酸重碳酸型或重碳酸硫酸型、重碳酸型主要分布在淡水区。
Based on the monitoring data of 108 groundwater wells in the north and east and west of Liaodong Bay, this paper comes to the conclusion:(1) The severe seawater invasion areas of Liaodong Bay mainly distribute in the north of Liaodong Bay. It shows a belt type of the severe seawater invasion areas and light degree seawater invasion areas from shore to land, but in the east and west of Liaodong Bay, the seawater invasion is severe, while most part of this area is lightly polluted;(2) The groundwater hydro ̄chemical type is divided into 5 kinds. It shows a belt type from shore to land and the disciplinarian of the type change reflects distribution features of seawater invasion obviously. Chloride type generally distribute in brackish to saline water area, bicarbonate ̄chloride type or chloride ̄bicarbonate type and bicarbonate ̄chloride ̄sulfate type or chloride ̄bicarbonate ̄sulfate type distribute in brackish to freshwater transition zone, bicarbonate ̄sulfate type or sulfate

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[目的]探讨小儿病毒性脑膜炎和结核性脑膜炎(TBM)早期鉴别因素。[方法]回顾性分析确诊为病毒性脑膜炎患儿262例和TBM患儿55例的临床和实验室特征。[结果]比较两种疾病临床和实验室特征,多变量分析表明:入院前症状持续时间(DSBA)、DSBA ≥5 d、死亡、脑脊液(CSF)与血浆葡萄糖比值<0.5、CSF氯化物浓度、CSF氯化物浓度低于正常、CSF蛋白值、CSF蛋白值>1 g/L有统计学意义(P<0.05);多变量 logistic 回归方程分析,进入 logistic 回归方程的因素:DSBA≥5 d、CSF与血浆葡萄糖比值<0.5、CSF氯化物浓度低于正常、CSF蛋白值>1 g/L;ROC 曲线提示:DSBA、CFS氯化物浓度、CFS蛋白值灵敏度高。[结论]早期获得的DSBA、CSF与血浆葡萄糖比值、CSF氯化物浓度、CSF蛋白值等临床和实验室的数据对于鉴别结核性脑膜炎和病毒性脑膜炎有重要意义。
[Obj ective]To explore the early identification factors between viral meningitis and tuberculous meningitis(TBM)in children.[Methods]Clinical and laboratory features of 262 patients with viral meningitis and 5 5 TBM patients were analyzed retrospectively.[Results]Clinical and laboratory features were compared between two diseases.Multivariable analysis showed that there were significant differences in duration of symptom before admission(DSBA),DSBA>5 days,death,cerebrospinal fluid(CSF)glucose/blood glucose ratio 1g/L(P 5 days,CSF glucose/blood glucose ratio 1 g/L.ROC curve indicated that DSBA,CSF chloride concentration and pro-tein had high sensitivity.[Conclusion]Early available clinical and laboratory data such as DSBA,CSF glu-cose/blood glucose ratio,CSF chloride and protein are important to differentiate TBM from viral meningitis.

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为回收甲烷氯化物生产中排空的一氯甲烷,提出了两种一氯甲烷回收工艺技术方案进行分析比较。根据甲烷氯化物生产现状选择了其中一种方案实施,可回收一氯甲烷,达到节能减排、提高资源利用率的预期效果。
This paper proposes two technical solutions on the recycling of the methane chloride when producing chloromethanes (CMS), and analyzes their differences. One of the two technical solutions could be taken accord-ing to the production status of CMS. Then finally it could realize our expectation of reducing the emission and higher the efficiency of resources utilization.

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采用热力学平衡计算和管式炉实验的方法对垃圾焚烧中氯化物对铜迁移转化特性的影响进行了研究。热力学平衡计算和实验研究结果表明,氯化物的形态、含量及焚烧温度对铜的迁移转化特性有显著影响。无论是有机PVC还是无机NaCl对铜都有氯化作用,使其生成易蒸发的CuCl,从而促进铜向飞灰中的迁移分布,NaCl的影响大于PVC。焚烧温度、氯化物的热解特性与焚烧方式协同作用影响铜的迁移转化特性,随温度升高PVC的氯化作用减弱而NaCl的作用增强。焚烧时间对PVC没有显著影响,对NaCl的影响显著。扫描电镜–能谱分析(SEM-EDS)结果显示,添加PVC时铜在底渣中以氧化物的形态存在,而添加NaCl时铜以氧化物和氯化物的形态共存,飞灰中铜以氯化物的形态存在于小颗粒中。
The effects of chlorides on the Cu partitioning and speciation in the municipal solid waste (MSW)incineration was investigated using thermodynamic equilibrium calculation and a simulated tubular furnace experiment. The thermodynamic calculation and experimental results show that the form and amount of chloride and the temperature impacted significantly on the Cu partitioning and speciation. Both organic PVC and inorganic NaCl could chlorides copper to form volatile CuCl, as a result, it promotes Cu distribution in fly ash. The NaCl had a more significant effect than the PVC does. The combustion temperature and properties of pyrolysis and combustion of chloride affected Cu partitioning and speciation synergistically. As the temperature increased, the chlorization effect of PVC decreased, whereas the chorization effect of NaCl increased. Incineration time had apparent influence on NaCl but almost no influence on PVC. The results of SEM-EDS show that Cu is present as oxide in bottom ash w
采用分光光度法对羧甲基淀粉钠中氯化物含量定量分析,研究了测量波长及反应时间对吸光值的影响。在检测波长342nm、反应时间为40min时定量测定羧甲基淀粉钠中氯化物含量,并与国标法进行了对比。
This paper carries on the quantitative analysis on the chloride content of carboxymethyl starch sodium using the spectrophotometry and studies the influence of the measuring wavelength and the reaction time on the absorption value. When the detecting wavelength is 342nm and the reaction time is 40min, the chloride content in carboxymethyl starch sodium is detected quantificationally, and it''s compared with the national standard method.

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以甲烷氯化物建设项目环评为研究对象,通过从产业政策、工程分析、环境风险、清洁生产、污染防治、厂址可行性等角度对其特点进行分析,提出了甲烷氯化物建设项目环评工作的重点和难点,并结合实际环评工作,给出了相应的解决方法和思路。
This paper studies environmental impact assessment of methane chlorides construction projects to analyze its characteristics and raise its emphasises and difficulties ,from industrial policy, engineering analysis, environmental risks, cleaner production, pollution prevention, site feasibility. What’s more,it’s also provide some method and suggestion to solve emphasis and difficulties.

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本文论述了一种锅炉水中pH值、碱度和氮化物连续测定方法-连续电位滴定法。该方法在一次取样后,连续进行pH值、碱度和氯化物的电位滴定,并获得pH值、酚酞碱度、甲基橙碱度和氯化物浓度。该方法比常规方法的测试时间缩短一半,设备利用率提高一倍。
This article discusses the continuous determination method for the value of a boiler water pH, alkalinity, and chloride-continuous potentiometric titration. A sample was tested through this and the value of pH, phenolphthalein alkalinity, methyl orange alkalinity and chloride concentration were obtained continuously. The testing time adopting this method is shortened by half than the conventional one, it also doubles the equipment utilization rate.

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为了帮助电镀企业选择适合的三价铬镀铬体系,通过实验探讨了3种已获应用的三价铬镀铬溶液体系(硫酸氯化物和硫酸-氯化物)与六价铬镀铬溶液体系在镀铬过程中镀液性能、镀层外观色泽和性能之间的差异。结果表明,3种三价铬镀铬体系的电流效率均高于六价铬镀铬体系,所得铬镀层与镍镀层的结合力均好,但镀层硬度较低。其中,硫酸镀铬体系的分散能力和覆盖能力最好,得到合格镀层的电流密度范围最宽,所得铬镀层外观色泽乌亮,其耐蚀性与六价铬镀铬相当,但镀速较慢。硫酸-氯化物溶液体系镀速较快,电流效率最高;氯化物溶液体系次之,所得铬镀层外观色泽均白亮,但耐蚀性稍差。
The difference of the bath property as well as the appearance, color, luster and performance of chromium deposit obtained from three types of applied trivalent chromium baths including sulfate, chloride, and sulfate-chloride systems from that prepared from a hexavalent chromium plating bath was discussed to help the electroplating corporations selecting suitable trivalent chromium plating system. The results proved that the cathodic current efficiency of all the trivalent chromium plating systems is higher than that of the hexavalent chromium plating system. The adhesion of trivalent chromium deposits to nickel deposit is good, while the hardness is relative low. The sulfate trivalent chromium plating system features the highest throwing power and covering power, the widest current density range over which an eligible chromium deposit is obtained, but relatively low deposition rate, and produces deposits with glossy black appearance and comparable corrosion resistance to the hexavalent

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