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双语推荐:Chemical

在日益增长的能源需求与日益严峻的全球气候变化带来的双重压力下,清洁、高效且经济的能源利用方法显得尤为重要。将化学链概念用于传统化石能源的转化是一种前景广阔的新技术。化学链燃烧利用载氧体间接转化含碳燃料,同时实现二氧化碳的捕集。俄亥俄州立大学研发了采用铁基载氧体和移动床反应器的化学链技术,可实现天然气、煤、生物质等多种燃料向电力、氢、液体燃料等产品的零排放转化。目前,合成气化学链(syngas chemical looping,SCL)和煤直接化学链(coal direct chemical looping,CDCL)技术两套25 kWth级小试装置已成功运行总计超过850 h,一套250 kWth级的高压SCL装置即将投入示范运行。
Driven by increasing demands for energy and concerns for climate change, more attention are paid to the development of clean, efficient, and economical technologies for energy conversion, among which chemical looping is considered as a promising alternative for fossil fuel conversion. Chemical looping processes enable highly efficient in situ CO2 capture in oxidation of carbonaceous fuels by making use of solid oxygen carriers. The Ohio State University (OSU) has developed a unique chemical looping technology utilizing iron-based oxygen carrier and moving bed reactors. Thermodynamic analysis shows that counter-current moving bed reactor can maximize oxygen carrier conversion while fully converting fuels, enabling high purity H2 production by iron-steam reaction. OSU chemical looping is highly flexible for converting a variety of gaseous and solid fuels to electricity, H2, and chemicals with CO2 captured. To date, the syngas chemical looping (SCL) technology and the coal direct chemical

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化学武器作为大规模杀伤性武器使用于战场上始于20世纪第一次世界大战期间。为了全面禁止化学武器,国际社会于1993年缔结了《禁止化学武器公约》(Chemical Weapons Convention,CWC)并于1997年生效。迄今为止,全球仅有7个国家未缔约。世界攻防格局从此发生改变,开始进入后化学武器时代。化学恐怖袭击是后化学武器时代的世界所面临的重要化学威胁。该文通过对具体化学恐怖袭击事件的经验总结,对化学恐怖袭击的可能性、来源、类型和未来发展趋势进行了分析,并提出了对当前化学恐怖袭击的应对策略。
Chemical weapons(CW), as weapons of mass destruction on the battlefield , made their debut in the First World War of the last century .To achieve total prohibition on CW , the international community concluded the Chemical Weapons Convention(CWC)in 1993, and it came into force in 1997.So far, only seven countries have been outside the CWC.The offensive and defensive pattern of the world changed then , and the world began to enter the post-CW era.A chemical terrorist attack perspective is needed in consideration of chemical threats facing the world .This article summarizes the experience on specific chemical attacks , analyzes the possibility , sources, types and developments of a chemical terror-ist attack, and puts forward countermeasures for any possible chemical terrorist attack .

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饮料生产设备使用热水和碱液的传统清洗消毒方式,会造成大量的蒸汽、化学药品(氢氧化钠)、水的耗用,并且增加了生产制造成本,企业在追求效益的同时需要降低生产成本和减少环境的污染。采用一种新的电解活化水(Electro-Chemical Activation Water,ECA))清洗消毒代替传统的清洗消毒方式,将有助于降低生产成本,减少对环境的污染,并且清洗效果及运行良好稳定。
Traditional cleaning and disinfection methods (hot water and lye)used for beverage production equipment will lead to great consumptions of steam,chemical(sodium hydroxide)and water and increased manufacturing costs. So,bev-erage companies need to focus on the reductions of production costs and environmental pollutions besides the pursuit of profits. New electro-chemical activation water (ECA)used in cleaning and disinfection instead of the traditional methods will help to reduce production costs and environmental pollutions,and good cleaning effect and stable operation have been proved.
Chemical interaction of Ce-Fe mixed oxides was investigated in methane selective oxidation via methane temperature programmed reduction and methane isothermal reaction tests over Ce-Fe oxygen carriers. In methane temperature programmed reduction test, Ce-Fe oxide behaved complete oxidation at the lower temperature and selective oxidation at higher temperatures. Ce-Fe mixed oxides with the Fe content in the range of 0.1–0.5 was able to produce syngas with high selectivity in high-temperature range(800–900 °C), and a higher Fe amount over 0.5 seemed to depress the CO formation. In isothermal reaction, complete oxidation occurred at beginning following with selective oxidation later. Ce1–xFexO2–δ oxygen carriers(x≤0.5) were proved to be suitable for the selective oxidation of methane. Ce-Fe mixed oxides had the well-pleasing reducibility with high oxygen releasing rate and CO selectivity due to the interaction between Ce and Fe species. Strong chemical interaction of Ce-F
Chemical interaction of Ce-Fe mixed oxides was investigated in methane selective oxidation via methane temperature pro-grammed reduction and methane isothermal reaction tests over Ce-Fe oxygen carriers. In methane temperature programmed reduction test, Ce-Fe oxide behaved complete oxidation at the lower temperature and selective oxidation at higher temperatures. Ce-Fe mixed oxides with the Fe content in the range of 0.1-0.5 was able to produce syngas with high selectivity in high-temperature range (800-900 °C), and a higher Fe amount over 0.5 seemed to depress the CO formation. In isothermal reaction, complete oxidation oc-curred at beginning following with selective oxidation later. Ce1-xFexO2-δ oxygen carriers (x≤0.5) were proved to be suitable for the selective oxidation of methane. Ce-Fe mixed oxides had the well-pleasing reducibility with high oxygen releasing rate and CO selec-tivity due to the interaction between Ce and Fe species. Strong chemical interaction of Ce-

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以电子辅助热丝化学气相沉积(Electron-assisted Chemical Vapor Deposition,EACVD)一体化系统为研究对象,根据金刚石沉积过程中对衬底温度的要求,设计了模糊PID衬底温度控制系统。使用结果表明:该系统对化学气相沉积( CVD)金刚石的衬底温度参数控制精确,能够长时间稳定运行,可以制备出高质量的CVD金刚石涂层。
According to the requirement for the temperature in the deposition of the diamond ,a fuzzy-PID compound control meth-od was established in the integration Electron-Assisted Chemical Vapor Deposition ( EACVD) system.The experiment of CVD dia-mond deposition shows that the process parameters can be accurately controlled and the system can apply stable long -term opera-tion.It can be used for the deposition of high quality CVD diamond coating .
利用化学杂交剂(Chemical Hybridization Agent,CHA)诱导小麦雄性不育配制杂交小麦新品种已成为近来年小麦杂种优势利用的有效途径,目前广泛使用的GENESIS和SQ-1已初步实现了小麦杂交种规模化。随着现代分子生物学技术的发展,CHA诱导小麦雄性不育机理的研究获得重要进展。为了对小麦新型化学杂交剂的研究与开发提供理论基础,从细胞学、活性氧代谢、泛素/蛋白酶体途径、能量代谢等方面综述CHA诱导小麦雄性不育机理的研究进展。
In recent years,it was an extremely effective way that the male sterility was induced by chemical hybridizing agent,and used to produce new varieties of hybrid wheat.The production of hybrid seeds was large-scale by GENESIS and SQ-1 . With the development of modern molecular biology technology,the study that the mechanisms of male sterility induced by CHA in wheat access an important progress.The author introduce the research progress of several CHA and the mechanisms of male sterility induced by CHA,from the aspects of cytology,active oxygen metabolism,the ubiquitin/proteasome pathway,energy metabolism et al,so as to provide a theoretical basis for the research and development of new wheat chemical hybridizing agent.

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为保证加拿大的食品安全,加拿大政府建立了完善的食品监管体系。作为监控体系的重要表现形式,加拿大政府制定并实施涵盖内容广泛、形式多样的食品安全监控计划,这些计划的主要构成是食品抽样和检测行动(sampling and testing activities),该行动分为监控抽样、基于风险的抽样、定向抽样、合规检测、目标调查和法律抽样,以监控食品中的病原微生物、化学残留及污染物,其中涉及化学残留控制计划的行动涵盖了除“基于风险的抽样”之外的其他5个种类。本文选取了2种典型的控制计划:全面系统的国家残留监控计划(national chemical residue monitoring program, NCRMP)和灵活针对性强的目标调查,详细介绍了NCRMP的法律背景、统计学依据、抽样化合物确定模型、抽样结果报告、结果应用等内容,并简要介绍了目标调查;最后分析了加拿大监控体系的特点。旨在帮助我国政府部门和企业了解加拿大的化学残留监控体系和制度。
ABSTRACT:The Canadian government operates a perfect food safety program designed to ensure that food available to Canadians is safety. As the major manifestation of monitoring system, Canadian government designs and implements comprehensive, diversified food safety monitoring plans, which consists of food sampling and testing activities. The activities are classified as 6 different types: monitoring sampling, risk-based sampling, directed sampling, compliance testing, targeted surveys and legal sampling in order to monitor pathogenic microorganism, chemical residues and contaminants. The five types are related to chemical residue control program except risk-based sampling. The paper chose the two typical programs: comprehensive and systematic national chemical residue monitoring program (NCRMP) and flexible and to the point targeted surveys, elaborated NCRMP’s legal authority, statistical considerations, risk priority compound model, sampling result report and result applica
本文全文译自欧洲标准EN 13804:2013(E)Foodstuffs - Determination of elements and their chemical species - General considerations and specific requirements。该标准规定了食品中元素及其形态测定的一般考虑和特殊要求,概述了从实验室接收样品到最终结果的过程。该标准内容主要包括:样品制备中的注意事项和要求,如试剂、器具、设备及样品储存要求;痕量元素分析的特殊要求,如对所用试剂、标准物质、容器及设备等的要求;方法准确度评估指标的计算,如检出限和定量限、方法偏离评估和回收率及测定不确定度等的计算;质量控制措施,如定期参加能力测试(PT)、定期使用标准物质(RM)或有证标准物质(CRM)以及如何使用等;还包括测试结果的表达形式以及测试报告应包含的内容。
This paper is the translation of the European standard EN 13804:2013: Foodstuffs - Determina-tion of elements and their chemical species - General considerations and specific requirements. This standard specified the general considerations and special requirements for the determination of elements and their chemical species in food, including a process from receiving samples by the laboratory to the final test result. It mainly included the considerations and specific requirements such as reagents, apparatus, equipment and sto-rage requirements in the sample preparation and such as reagent, standard substance, containers and equipment in the analysis of trace elements in food, included the calculation method of the detection limit, quantitative limit, recovery rate and the measurement uncertainty,etc., included the quality assurance methods such as pro-ficiency testing schemes(PT), using standard material (RM) or certified standard material (CRM). It also in-cluded the expres

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极性有机化合物整合采样技术( Polar organic chemical integrative samplers,POCIS)适用于极性有机污染物的采集,随着新型极性有机污染物的不断出现,该技术已经引起了科学家的广泛关注。本文概述了几种常用的被动采样装置,重点介绍了POCIS采样器的一般结构、富集原理、环境因素如流速、温度、pH、溶解性有机质、盐度及膜的污染等对采样速率的影响,讨论了针对极性物质检测的质量控制和保证以及性能参考物质,综述了POCIS在水环境有机污染物监测中的应用。最后,本文对POCIS的应用前景进行了展望。
Polar organic chemical integrative samplers ( POCIS ) are suitable for the sampling of polar organic pollutants in the aquatic environment. POCIS have evoked extensive attention recently with the occurrence of emerging polar organic pollutants. This review first overviewed the advantages and shortcomings of several popular passive sampling devices; and then focused on the basic structure, modeling and principles of sampling and effects of environmental factors including flow rate, temperature, pH, DOM, salinity and membrane fouling on the sampling rate(RS)of POCIS. Then quality assurance and quality control as well as performance reference compounds for polar organic compounds were discussed. The applications of POCIS in the monitoring of organic pollutants in the aquatic environment were reviewed. Finally, the prospect in this research field was discussed.
对自主研发的多羟多胺络合剂(FA/O)在硅通孔技术(Through-silicon-via,TSV)化学机械平坦化(chemical mechanical planarization,CMP)进行了应用研究。结果表明,FA/O络合剂较其它常用络合剂在碱性CMP条件下对铜有较高的去除速率,抛光液中不加FA/O络合剂时,铜的去除速率仅为45.0nm/min,少量FA/O的加入迅速提高了铜膜去除速率,当FA/O含量为50mL/L时,铜去除速率趋于平缓。在TSV Cu CMP中应用表明,FA/O对铜的去除率可高达2.8μm/min,满足微电子技术进一步发展的要求。
A polyhydroxy polyamino complexing agent (FA/O)has been developed and applied in through-sili-con-via (TSV)chemical mechanical planarization (CMP).The comparision experiment of FA/O with another normal complexing agents has been carried out,the results reveal that FA/O has a efficient effect on removal of copper in alkaline condition,few FA/O added in slurry will significantly improve the removal rate of copper. However,when we continue to add FA/O in solution,the removal rate of copper will stay leveling.The result of TSV Cu CMP reveal that the removal rate of copper can be achieved 2.8μm/min,it can meet the require-ment of development of microelectronic technology.

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